builderFactory.setFeature("http://apache.org/xml/features/validation/schema", true);
        builderFactory.setFeature("http://apache.org/xml/features/validation/schema-full-checking", true);

import org.w3c.dom.Document;

import javax.xml.parsers.DocumentBuilder;
import javax.xml.parsers.DocumentBuilderFactory;
import java.io.FileInputStream;

/**
 * This class represents ...
 */
public class SchemeValidation {
    public static void main(String[] args) throws Exception {
        DocumentBuilderFactory builderFactory = DocumentBuilderFactory.newInstance();
        builderFactory.setValidating(true);
        builderFactory.setNamespaceAware(true);
        builderFactory.setFeature("http://apache.org/xml/features/validation/schema", true);
        builderFactory.setFeature("http://apache.org/xml/features/validation/schema-full-checking", true);
        DocumentBuilder builder = builderFactory.newDocumentBuilder();
        Document document = builder.parse(new FileInputStream(args[0]));
        System.out.println(document);
    }
}

<?xml version="1.0" encoding="UTF-8"?>
<shiporder orderid="889923"
xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"
xsi:noNamespaceSchemaLocation="shiporder.xsd">
  <orderperson>John Smith</orderperson>
  <shipto>
    <name>Ola Nordmann</name>
    <address>Langgt 23</address>
    <city>4000 Stavanger</city>
    <country>Norway</country>
  </shipto>
  <item>
    <title>Empire Burlesque</title>
    <note>Special Edition</note>
    <quantity>1</quantity>
    <price>10.90</price>
  </item>
  <item>
    <title>Hide your heart</title>
    <quantity>1</quantity>
    <price>9.90</price>
  </item>
</shiporder> 

<?xml version="1.0" encoding="UTF-8" ?>
<xs:schema xmlns:xs="http://www.w3.org/2001/XMLSchema">

<xs:element name="shiporder">
  <xs:complexType>
    <xs:sequence>
      <xs:element name="orderperson" type="xs:string"/>
      <xs:element name="shipto">
        <xs:complexType>
          <xs:sequence>
            <xs:element name="name" type="xs:string"/>
            <xs:element name="address" type="xs:string"/>
            <xs:element name="city" type="xs:string"/>
            <xs:element name="country" type="xs:string"/>
          </xs:sequence>
        </xs:complexType>
      </xs:element>
      <xs:element name="item" maxOccurs="unbounded">
        <xs:complexType>
          <xs:sequence>
            <xs:element name="title" type="xs:string"/>
            <xs:element name="note" type="xs:string" minOccurs="0"/>
            <xs:element name="quantity" type="xs:positiveInteger"/>
            <xs:element name="price" type="xs:decimal"/>
          </xs:sequence>
        </xs:complexType>
      </xs:element>
    </xs:sequence>
    <xs:attribute name="orderid" type="xs:string" use="required"/>
  </xs:complexType>
</xs:element>

</xs:schema>