Locale support is automatically initialized when a database cluster is created using initdb
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LC_COLLATE and LC_CTYPE settings are determined at initdb time and cannot be changed without repeating initdb



Although you can specify any encoding you want for a database, it is unwise to choose an encoding that is not what is expected by the locale you have selected. The LC_COLLATE and LC_CTYPE settings imply a particular encoding, and locale-dependent operations (such as sorting) are likely to misinterpret data that is in an incompatible encoding.

Since these locale settings are frozen by initdb, the apparent flexibility to use different encodings in different databases of a cluster is more theoretical than real. It is likely that these mechanisms will be revisited in future versions of PostgreSQL.

One way to use multiple encodings safely is to set the locale to C or POSIX during initdb, thus disabling any real locale awareness