http://dev.mysql.com/doc/refman/5.5/en/join.html If there is no matching row for the right table in the ON or USING part in a LEFT JOIN, a row with all columns set to NULL is used for the right table. You can use this fact to find rows in a table that have no counterpart in another table:

SELECT left_tbl.*
FROM left_tbl LEFT JOIN right_tbl ON left_tbl.id = right_tbl.id
WHERE right_tbl.id IS NULL;

This example finds all rows in left_tbl with an id value that is not present in right_tbl (that is, all rows in left_tbl with no corresponding row in right_tbl).