Выдержка из документации
shell> mysql --user=root mysql
mysql> GRANT ALL PRIVILEGES ON *.* TO monty@localhost
IDENTIFIED BY 'some_pass' WITH GRANT OPTION;
mysql> GRANT ALL PRIVILEGES ON *.* TO monty@"%"
IDENTIFIED BY 'some_pass' WITH GRANT OPTION;
mysql> GRANT RELOAD,PROCESS ON *.* TO admin@localhost;
mysql> GRANT USAGE ON *.* TO dummy@localhost;