ALTER DATABASE database
{ ADD FILE < filespec > [ ,...n ] [ TO FILEGROUP filegroup_name ]
| ADD LOG FILE < filespec > [ ,...n ]
| REMOVE FILE logical_file_name
| ADD FILEGROUP filegroup_name
| REMOVE FILEGROUP filegroup_name
| MODIFY FILE < filespec >
| MODIFY NAME = new_dbname
| MODIFY FILEGROUP filegroup_name {filegroup_property | NAME = new_filegroup_name }
| SET < optionspec > [ ,...n ] [ WITH < termination > ]
| COLLATE < collation_name >
}

ALTER DATABASE database REMOVE FILE logical_file_name - если мне память не изменяет.