Microsoft SQL Server  2005  -  9 . 00 . 5000 . 00  (X64)   Dec  10   2010   10 : 38 : 40    Copyright (c)  1988 - 2005  Microsoft Corporation  Standard Edition ( 64 -bit) on Windows NT  6 . 0  (Build  6002 : Service Pack  2 )

DECLARE @cmd nvarchar( 400 )
SET @cmd = N'C:\Report\Blank.exe'
exec master.dbo.xp_cmdshell @cmd

using System;
using System.Collections.Generic;
using System.IO;
using System.Linq;
using System.Reflection;
using System.Text;
using Word = Microsoft.Office.Interop.Word;

namespace Blank
{
    class Program
    {
        static void Main(string[] args)
        {
            Word._Application AppWord = new Word.Application();
            Word._Document WordDoc = null;

            Object oFalse = false;
            Object oMissing = Missing.Value;
            Object oTemplatePath = @"C:\TMP\1.doc";
            Object fileFormat = (Object)Word.WdSaveFormat.wdFormatDocument;
            try
            {
                WordDoc = AppWord.Documents.Add(ref oTemplatePath, ref oMissing, ref fileFormat);
                Object oSaveAsFile = @"C:\TMP\SampleDoc.doc";
                WordDoc.SaveAs(ref oSaveAsFile, ref fileFormat);
            }
            catch (Exception ex)
            {
                Console.WriteLine(" #1 " + ex.Message);
            }
            finally
            {
                if (WordDoc != null)
                    WordDoc.Close(ref oFalse, ref oMissing, ref oMissing);

                if (AppWord != null)
                    AppWord.Quit(ref oMissing, ref oMissing, ref oMissing);
            }
        }
    }
}